Researchers at UNSW have developed a new, sustainable way to break down plastics using sunlight, air, and a common chemical called iron trichloride (ferric chloride). This innovative approach could revolutionize plastic recycling and reduce the amount of microplastics in the environment.

Related work from the research team that shows polystyrene breaking down in solvent. The published research in this story differs as the polymers in those experiments were already dissolved. PHOTO: UNSW – Maxime Michelas and Cyrille Boyer
How the Process Works
The new method uses ferric chloride, a cheap and widely available chemical, combined with exposure to sunlight and oxygen to degrade plastics quickly and effectively. This process can break down seven types of polymers by 90% in less than 30 minutes and up to 97% after three hours.
The steps include:
- Dissolving the Polymer: The plastic must first be dissolved using a solvent. This step prepares the polymer for degradation.
- Exposure to Ferric Chloride and Light: Once dissolved, the solution is exposed to ferric chloride and a light source. The chemical reaction triggered by light and oxygen breaks down the polymer chains, gradually turning the solution clear.
- Conversion to Raw Material: The final product can serve as a raw material for other products or be further broken down by bacteria, making it a potentially circular and sustainable approach to plastic waste.
Key Benefits of the New Method
- Low Energy and Cost-Effective: Unlike other plastic degradation methods, this process works at room temperature and does not require expensive equipment or high energy input. Ferric chloride is affordable and easy to obtain, making the method accessible for large-scale use.
- Quick Degradation: The ability to break down plastics by up to 97% in just a few hours makes this process faster than traditional recycling methods. This rapid degradation is particularly useful for tackling the growing issue of plastic pollution.
- Environmentally Friendly: The use of sunlight and air as main components makes this process more environmentally friendly compared to conventional plastic recycling methods, which often involve toxic chemicals and high temperatures.
- Potential for Microplastic Reduction: This breakthrough offers a promising solution for reducing the amount of microplastics in the environment. By breaking down plastics into smaller, manageable components, it opens the door to new ways of recycling and reusing plastic waste.
Challenges and Future Improvements
While this method shows great promise, there are some limitations:
- Use of Solvents: The process currently relies on solvents to dissolve the plastic before degradation. This step is not compatible with water, which presents challenges for treating plastic waste that is often found in aquatic environments.
- Need for New Catalysts: Researchers are working on finding new catalysts that can operate in water, which would make the process even more versatile. They are also exploring ways to degrade plastics without the use of solvents, further enhancing the environmental benefits.
- Scalability and Real-World Application: For the method to be widely adopted, it needs to be tested on a larger scale to ensure it can handle the vast amount of plastic waste generated globally. Researchers are optimistic that with further development, this approach could become a cornerstone of sustainable plastic recycling.
A Step Forward in Sustainable Plastic Recycling
This innovative approach to breaking down plastics using sunlight, air, and ferric chloride represents a significant step forward in sustainable recycling. As researchers continue to refine the process, it has the potential to revolutionize how we manage plastic waste, offering a low-energy, cost-effective, and environmentally friendly alternative to traditional recycling methods.
By addressing the limitations and expanding the application of this technology, it could soon play a crucial role in reducing plastic pollution and promoting a more sustainable future.
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